ok couple of things. I would just like to point out that i was a sasuke fan, all the way through itachi arc. Hated itachi's guts for being a ****, but i still admired him, because of his strength. After the Itachi arc, since he formed Taka, i have really hated sasuke, cause he became extremely dumb, in common sense and battle wise. He is just now begining to act like an adult, so please don't make threads just to let people gang up on him. now that thats out of the way, let's talk logic.
I'll give you first point,, even if sasuke's flame control is a lot slower than Itachi's i don't believe amaterasu can be absorbed. That's just a speculation so it could go either way.
As we say, pain is susceptible to Genjutsu, demonstrated by Jiraiya and Fukasaku, so now it's a matter of IF he'll catch him, because, level at which Sasuke performs Genjutsus is a Farcry from Itachi who can cast genjutsu just by lifting a finger. Dojutsu wise, also. Sasuke's genjutsu is nothing compared to Itachi's Tsukuyomi, the second strongest eye based genjutsu in Narutoverse after KA, so even if he catches them in Genjutsu, they mightbe able to break out. once again could go either way.
I'll give you Susanoo, especially EMS one, with all the amaterasu spamming blades and arrows, it would be impossible for him not to get couple of pains.
KIRIN!. i feel this jutsu is overhyped too much because people think it destroyed itachi with his susanoo. If you read upon the manga, Itachi was able to stop a full power Kirin, with just Susanoo's ribcage, so in terms of power, Mei's Lava might be stronger than Kirin, plus don't forget, Kirin is still an elemental jutsu and not etherreal flames like amaterasu, so Preta path should be able to absorb it easily, considering the things it has absorbed. After that, there's still Deva path to be dealed with. Only thing we have seen that is capable to break through Shinra Tensei was 6 tails Naruto, Barely too, and the 30 clones you mentioned was a defense on naruto's side, he did not break through, clones absorbed the attack, aka human shields, and as soon as attack was over, he used that 5 second window to Rasengan Deva Path's ass. Still if Sasuke manages to get through Shinra Tensei, IF he's not a whining kid and plans like he did vs Deidara, there is still question of Chibaku Tensei and Basho tenin. If we disregard Universal pull on the grounds that it simply can not pull susanoo, Chibaku Tensei will still dominate it since, 8 tailed Naruto barely got out of it, and pain said he could make it stronger. And let's face it, Sasuke is no itachi, to tell a techniques weakness in a sec, that was unique to his brother which does not pass down with the eyes. Even if he does have knowledge on Chibaku Tensei, Sasuke hasn't demonstrated any techs strong enough to break through. Susanoo's arrows don't seem that strong to tell you the truth, they are fast but in this case, power is more useful than speed.
If you read this, know i am not saying sasuke does not stand a chance, i'm just saying it could go either way, i'm not sure. I hope you enjoyed it, i am open for debates