We haven't even seen Buckbeard do anything yet, he lost before to Yamamoto so he isn't stronger than.
Shunsei, Unohana, Kisuke, Genryusai, Yoruichi, and Ukitate are all people whose bankai are yet to be seen and the only thing we know about any of their bankai's, is that Shunsei's must be very wide scaled and very powerful for Ukitake to stop him from using it in the fight against Aizen.
If anything the strongest probably ought to be Kenpachi, he's so damn powerful when he releases his eye patch ad doesn't even use his Shikai. It just doesn't seem fathomable that Ichigo is the strongest shinigami, he's only been a soulreaper for a few years. While Unohana and Shunsei have been around for 100+ some years, captain level at that. How could Ichigo be stronger than the captains that have been fighting and gaining experience for who knows how long? but the anime is about Ichigo.
Yamamoto is the head captain though, so he probably is the strongest. Next to Kenpachi and Shunsei xD