Being good at chakra control is not getting you out of Tsukyomi... Tsukyomi (itachi's) cannot be cancelled.. this has been stated like what ? twice in the manga?
You can't kai method out because it lasts 1 second, it starts and ends in an instant, and in that duration, you feel the full effects of the jutsu
But no wories.. I'm sure if they fought kishi would find another way to make madara break Itachi's tsukyomi, but kai is impossible
Sir, the time to break out of Genjutsu depends on the Genjutsu time not real world time.
Pumping chakra is a real time activity.. not mental