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Itachi lacked chakra reserves, madara fought senjus for 24 hours, so...
Wrong, Itachi's sickness affected his chakra reserves.. but naturally, Itachi already showed he had abormally high chakra reserves.. the very fact that itachi
How do we know this? Kakashi stated genins normally don't have enough chakra to use a katon such as Gōkakyū no Jutsu... Sasuke learned the jutsu at 7, and it was stated that Itachi mastered it at an unknown age before that... meaning, since birth, Itachi , and most uchiha have above average chakra reserves, just as the Senju..... this would be because they are all born with exceptional amounts of Mental energy(passed down by the elder son), and mental energy is half the equation needed to create chakra
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a few things changed mangawise would be needed for Itachi to have surpassed Madara.... His pacifistic attitude removed, his sickness cured and his Sasuke, the one thing he loved above all dying. that death would be emotional loss needed to tip him off the edge and send him down the path of hate which correlates with power for uchihas ...