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I believe Madara can pull out his PS and attack with its sword in conjunction with his Katon attacks. This is require obito to remain intangible for 5 minutes, then he can take him out with PS slash, as in Konan's case it was made obvious that Obito cannot go intangible immediately after exhausting his 5 minutes. Otherwise, he wouldn't he resorted to Izanagi. That's how I see it.