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Itachi has probably more IQ than Shikamaru which is above 200.. Itachi can probably assasinate all the members of akatsuki specially Orochimaru when he tried to take his body.. The zetsu which was keeping an eye on Itachi can be assasinated too by capturing him in genjutsu or the sword of his Susanoo but why Itachi didn't killed them all? Why he left Orochimaru even??
Itachi wanted everyone to believe he's a criminal but deep inside he yearned for peace & he let go of Orochimaru as he was not much of a threat to Itachi at that time. Killing zetsu would only attract unwanted attention towards Itachi from the Akatsuki.