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Zetsu is still fairly powerful without Yamato. AN example of a way to take him out would be to plant spores on him, something ha managed to do to five Kage level shinobi at once without them noticing. While most of them managed to get rid of them quite easily, Hidan doesn't possess any ninjutsu to remove them, and would be forced to try to use his scythe. However, we do not know how effective that'd be, since a ember of the Seven Swordsman was vulnerable to the attack, and needed help to get rid of the clones.Zetsu without Yamato is fodder in battle. He isn't a fighting type... If they where to fight Hidan would take care of him and the clones with his scythe.