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Oh god lol re-read the manga. Ao noticed Danzo using it, and pointed it out to everyone. Danzo then stopped using KA on Mifune because he didn't want to arouse further suspicion.
When itachi made the crow use KA, he programmed it with an instruction, rather than make it completely control sasuke. Similarly, Danzo would only need to make milfune make him the Shinobi alliance leader, so for all we know, KA can only make you do one thing.
Yes, Ao was the one who found that Danzo was using KA, but it stopped when he told mifune. Therefore, KA can only made someone do one thing, and if they discover that they are being manipulated, they stop doing it. If someone who is fighting danzo suddenly has an overwhelming desire to have a bath in Sulfuric Acid, they will find out that they are being controlled by KA pretty quickly, and thus not jump into the bath of Sulfuric acid that danzo has Provided.