Unless EMS Madara has 100% kurama on his side, I don't see him winning at all.
His PS slashes are only as powerful as a standard bijuudama, and naruto's BM has blocked the juubi's multi-mountainrange busting laser. On the other hand there is no way madara's PS is going to survive a super bijuudama that's just as big as his susanoo. Then on top of that, he's going to have to deal with KCM clones on the battlefield or in Naruto's chakra cloak spamming FRS from different angles.
Sasuke is definitely above killer bee with his enton arsenal, however a BM clone to block Sasuke's enton attacks with tails would easily give Bee the win here since Susanoo is in no way going to tank his machine-gun dama.