Why did you disable Sasuke's Susanoo and have Pain use Chibaku Tensei from the start? Anyway Naruto and Sasuke. Sage Naruto and his summons were able to beat all of the other paths without Sasuke, so I'm sure he could beat Deva path with Sasuke backing him up.
In the manga, Pain just used
Shinra Tensei to blow up Konoha. In this scenario that does not happen. Which means, unlike when Naruto fought Pain, he would have this skill from the first moment and be hella more powerful.
Also, I disabled Susanoo because at the time of the Pain fight, Sasuke didn't have it.
Seperate Note:
This thread is really bringing some stupid answers from some people. Those of you who've said Naruto & Sasuke easily, are deluded and could at least offer a decent reason why Pain, one the the manga's strongest, could be "easily" beaten by a duo who have not worked together for 3 years and frankly, both have flaws.
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Bum-Boys if I've ever seen em...xd