Itachi taught him what Izanagi and Izanami do and how it works during their fight with Kabuto. Sasuke also learned about the use of Izanami during his fight with Danzo.Scan of that bullshit, when did he teach Sasuke?
He has itachi's eyes so he is capable of using it. But he is not experienced in MS EMS Genjutsu. So can he use them? I think so. Will he? Probably not.
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