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Ty and SasuHina solos
This couple is a possibility, but only in the Limited Tsukiyomi (sp?) where Hinata is much more aggressive, both physically & sexually, & where Sasuke is a flirtatious playboy. In the main Naruto timeline, these two simply WOULD NOT get along well. Sasuke would remind Hinata of her father too much, due to his cold & standoffish demeanor. Sasuke, on the other hand, would likely resent Hinata due to her insecurities & constant need for encouragement & self-doubt caused by being compared to Neji all her life.
The one couple from the main timeline that surprised me was Ino & Sai. I don't really see how their two personalities would mesh, but Sai is enough of a blank slate to attribute group to him that would make it possible.