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He doesn't need to know its Amatersu. Once he sees a large amount of chakra in Sasuke's eyes, he will know its something big, and prepares to defend against. Its not slow when he performs the jutsu before Amatersu is casted. But even then, Kakashi can just snipe him off with Kamui at the start of the match.
what if it was him using susanoo arrow witch kakashi doton wall is useless to doesnt matter a kamui from the start is no faster than amaterasu from the start ends in a draw worst case scenario for sasuke best case for kakashi