I don't see why not, he is the original owner of the eyes, but he probably won't need those techniques, his one eyed Rindo Limbo push was like Shinra Tensei x 20
I think i misread your post but what i said still kinda applies, Pain had to split the powers of the sage up because he couldn't handle them all in one body, I don't think Madara will have that problem, plus he knows that Naruto at least has encountered and defeated Pain, so I'm sure he wouldn't resort to techniques that Naruto already has experience against.