He would have been killed by Kabuto. Kabuto killed itachi like 3 times in that fight before he even got izanami up and running. EMS doesn't really add anything better as seen by sasuke.
he only wants better stamina.
And for the record, let's assume EMS Sasuke's a good guy, having been persuaded to help the alliance. Please list what you think Itachi would change.
As for me, personally I think he'd give both Obito a hard time with Tsukiyomi. And also with proper teamwork with the Shinobi Alliance, he'd seal Madara with the Totsuka Blade.