Not really. Even if Hiruzen knows about all the ninjutsus of Konoha then that doesn't mean he can use it whichever he wants.
Here, "Know" means having all the knowledge about it.
Similar to how the shinobis analyze the opponents jutsu and tries to find a counter.
just like Sasuke found about Deidara's clay and weaknesses but that doesn't mean he can use them.
just like Konoha got to know about the techniques of Pain's paths, but that doesn't mean the strongest Konoha member will be able to use them.
Just like Kakashi got to know about Tobi's Kamui along with Naruto and Gai. But that doesn't mean Kakashi can go intangible or Naruto and Gai can use them.