If he was in the same position as Naruto, getting intel and having Deva Path weakened? I think he might be able to beat them all. Sasuke's fighting style is definitely equipped to take down Preta (expert Kenjutsu), he can take down Asura with a Chidori true spear by surprise, he'll figure out Human and Naraka path and take care of them easily while his summonings buy him time to do it without trouble and he can use his MS to take down Animal Path and its summonings. He could throw off Deva's timing with an Amatarasu or a Susano'o arrow as well. So only in the same scenario as Naruto, do I see Sasuke winning.
But if it's just MS Sasuke vs 6 Paths of Pain from the start with no restrictions on Deva, Sasuke would probably take down 4 of them IMO.