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No offence, but you kinda failed with your own logic.
By this neither Madara nor Sasuke should have EMS as the second MS came from a third party i.e Itachi and Izuna. But you stated "Pure Uchiha" So I'll say this is an exception.
Sasuke would last a good while but would ultimately loose imo, High Diff for Madara's win.
Obito could win because with both MS he could just rip Madara in half like Kakashi did to Deidara's arm.
Itachi, would put up a decent fight, probably as good as EMS Sasuke presuming he is at full health, if not probably low to med diff for Madara's win.
Most other Uchiha are fodder.
If we factor in Shisui's KA team Uchiha wins ext low-diff against Madara.
Kind of the same as Tsukuyomi, but it's possible to dispel it like Sasuke did but there is no dispelling KA.