Because Kakashi believed that Rasengan was useful if he could apply Raiton manipulation. Because he couldn't, he sticked to Raikiri/Chidori, so in his mind, teaching Sasuke Chidori is more effective. Also, keep in mind that it takes many, many years for one to learn elemental recomposition and apply it to Rasengan which already requires a maximum amount of shape manipulation. Time was likely a huge constraint and by trying to teach Sasuke a Lightning Rasengan would not have maximized their training time.
Kakashi didn't even consider this for Naruto until Kakashi suddenly stumbled upon a specific training method which was only suited for Naruto. He likely didn't have a training method that could help Sasuke achieve it in a short period of time.