Yes, Sasuke could light a ton of Amaterasu on the village from a distance, attack amidst the chaos, and use PS to finish the job. One swing of PS would wipe out half the village.
So sasukes old plan was to destroy the hidden leaf and of course that's leads us to imagine a naruto vs sasuke fight
But if naruto wasn't there? Could ems prevail In destroying the hidden leaf?
I personally think he would unleash a wave of amateratsu on the village and put an end to it :b
Sasuke's old plan was to go with Suigetsu, Karin, and Juugo but he broke up his team when he went wild with Hatred. Also you should take in the fact that Sasuke was being over confident, he thought he could take on Bee and capture him easily and he almost died 3x in the fight. He tried attacking the Kage summit.... A smart plan of waiting for Danzo when he is heading back to the leaf would have been the better approach but Sasuke was crazy with hatred and even thought he could solo A and had to be saved by Gaara.
There are a bunch of Anbu black opts with their own unique abilities and jutsus, Jounins such as Kakashi, Neji, Gai, Shikaku, Ino's dad, Choza, Hinata's dad, Ebiki, ect..., chunins like Lee, Sakura, Ino, Kiba, Shino, ect... Tsunade was still in coma at that time so I'm not counting her.
You do know it was Shikaku who was the brains of the whole Shinobi alliance right? He does have info on Sasuke and on Uchihas in general and he was the one to plan on the alliance to use storm jutsus to blind Madara and Obito, Hidden mist and the bugs to make the Sharingan unable to see.
You also have to remember that Sasuke has
NO training with his EMS so he wouldn't know how to go PS, how much power it has, or how long he can maintain it for. Sasuke can't burn the village down with Amaterasu when there are sealing jutsus that can seal it, Jiraiya isn't the only person skilled with seals from Konoha. There are sensors like Ino and her dad, Kiba's clan who can smell Sasuke's scent, Shino's clan's bugs which all can pin point where Sasuke is if he attacks from far. Attack and defend back and forth with an effective plan is what Shikaku might have done while Sasuke waste his chakra in complete Susanoo, Amaterasu/Enton, summonings and then he might push himself to awaken his PS but that's if Shino's clan bug haven't swarmed him or enter his body.
As the fight is happening, Naruto and Yamato would have been notified of the attack and would be on their way to help OR Oonoki, and his grandkids would have went to help instead since Naruto is suppose to be hidden with Bee, so Sasuke might have to fight against Dust element, lava element (his granddaughter), and Earth jutsus from the grandson. Plus Sand and Konoha are close so they might also send fights but since it takes 3 days on foot to travel, Gaara might go with Temari and Kankouro by flying there and making it in time to help.