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If you have some cash and a friend willing to assist then get some anaesthesia, a neuromuscular-blocking agent and potassium chloride. Get your friend to inject you with these in that precise order - the anaesthesia will put you to sleep, the nerve agent will stop you breathing and the potassium chloride will stop your heart.
Don't try shooting yourself in the head or heart - contrary to folk lore, neither would necessarily cause immediate death and may possibly be painful. If you can't get the anaesthesia you could probably overdose on prescription sleeping pills and get a friend to shoot you in the head for good measure.
So a bullet to the brain will hurt? But only for like a couple of seconds right?
