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hence why I said "specifically villains". You've listed K11 and the obvious parents.
Joking aside, Orochimaru has never shown any sexual tendency towards any gender.
Kimmimaro was not interested in Jugo sexually. He was his best-friend.
The ones you've listed are only a fraction of the total characters in the series.
Kimimaro was obsessed with Orochimaru. And there aren't very many well-developed villains in the series. No one would care about the love lives of Akatsuki members who got like 2 fights each.