Theoretically? I don't see why not.
If we go off what we see in the Manga then he might be able to. Itachi was able to defend with Susanno, even if Kamui takes longer to prep maybe Kakashi could do the same with his technique.
Here's the problem... Itachi shouldn't of been able to defend against that. The speed of lightning is ridiculously fast. By the time Itachi's mind was even registering that a lightning bolt is coming towards him it would of been too late. No time to acknowledge the attack, let alone set up a defence. It was Bs.
So really Kakashi shouldn't be able to as he'd be vaporized before he knows it. Kirin is too fast.