Yes, I got 90 or over in all my Math courses in High School and I'm taking Calculus in University as well.
As for your question, this isn't just Math, it's Chemistry related. The standard rules of Math don't apply. My plug-in isn't working at this present moment, but judging from your question, it has to do with significant digits, which was the reason number changed, as it was rounded up. This is all dependent on the numbers you use in your calculations, as the number with the least significant digits will dictate the number of significant digits you round to in your final answer (which is the same as the one with the smallest amount of significant digits).