Location: Pain Vs Naruto(in the middle of destroyed konoha)
Intel: Konan knows dat tsunade is a Sannin and she is a medical ninja of highest caliber....
Tsunade knows dat Konan is an akatsuki member and dat she cannot take her lightly....
Konan (the lady angel) Vs the legendary...
Both are the strongest konoichi of their respective villages....
Location: Gaara Vs kimimaru
Intel: Manga knowledge
both are standing at a dist of 20m....
my vote goes for Temari...