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Fire starts turning orange around 2100 degrees farenheight, the same temperature as the hottest lava. Fire is bright red at around 1800 degrees farenheight and aces was definitely past red. Yellow fire (which ace used in his attack against BB) is over 2500 degrees.
So how is akainu hotter if he isn't? It must be because he's liquid that's all
I know people disagree because it's giving Ace Haki but the only real logical explanation I can come up with is either Logia can control what parts of their body transform and Ace left his torso solid to take the punch from Luffy or Ace used haki in his midsection to slow the punch enough to save Luffy but it cost him his life.