Depends. There's no guarantee that Madara w/ half of Rikudou's Chakra would have an effective jutsu like Sasuke did and while Rikudou Hashirama would clearly be stronger than RSM Naruto, Naruto has the advantage of having all of the Bijuu's Chakra which can effectively strike Kaguya's weak-spot.
Because of this, Sasuke and Naruto would have a higher chance at tagging Kaguya, but the other duo has a better chance of actually reacting to Kaguya's attacks.