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I don't think he was confident enough before getting use to his Rinnegan before trying it.You must be registered for see images
Edit: Obviously this was before he showed PS with Naruto so Idk how his mindset was after that
Ems was called true power by itachi. After gaining ems, sasuke thought he above even 5 kages. After the scan, he fully acknowledged him as equal
This scan also imply ems sasuke would have a hard time surpressing kurama inside his body