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If you mean Tendo Pain, then you are right.
If you mean the six paths of pain, then not at all. Naruto had help from 6 toads, had 2 sage clones prepared Tendo couldn't attack for half the fight, he had intel from Katsuyu, and he still was defeated by the six paths of pain.
I third this, on a one on one, pain rofstlomps naruto. We have to remember that he has used a lot of chakra before and after the fight.