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Actually, I believe Sasori was going to kill orochimaru. Do you think he would go try to kill his former partner without thinking "I have no chance at winning." Why would Sasori teach Orochimaru about his poisons.
Mind you, only 3 people have the anti-dote. And they were either good medical Nin, or Sasori himself. Sasori, Chiyo, and Sakura. Do not imply Oro had antidotes to Sasori's poison, until you show me a scan.
Whether who would win is debatable, something I have argued too many times. We don't know if Orochimaru has an antidote for sure, but we cant conclude he didn't for the reason ive mentioned. Also, since the manga did credit Orochimaru for Sasuke being immune to most poisons, there is no proof he wouldn't be to Sasori's. Therefore, I would leave poison out of the debate completely.